Rob,
You might want to read the Custom Statistics Guide on the
documentation page for a general overview of how to create custom stats.
That said, for this particular stat you want to create a new column in the Holdem Cash Player Statistics section, call it cnt_bb_steal_call and give it the following value expression:
sum(if[ holdem_hand_player_statistics.flg_blind_b and holdem_hand_player_statistics.flg_blind_def_opp and lookup_actions_p.action LIKE 'C', 1, 0])
This counts up the number of times you: were in the big blind, had a steal defense opportunity, and your first action was fold (you could use the flg_p_fold field but then it'd count the times you 3-bet and folded to a 4-bet).
Then go to the stats tab, and the easiest place to start is likely duplicating the Fold BB to steal, you'll want to change the name, use your new column instead of cnt_bb_steal_fold, and change the description and title on the format tab appropriately. Save the stat, update your cache and you should be all set.
Edited: Fixed a couple of minor errors in the value expression.